Hydrothermal Liquefaction of Water Hyacinth: Effect of Process Conditions and Magnetite Nanoparticles on Biocrude Yield and Composition
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Date
2021
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Abstract
In this work, an efficient way of converting the water hyacinth to biocrude oil
using magnetite nanoparticles (MNPs) as potential catalysts was demonstrated
for the first time. MNPs were synthesised by co-precipitation and used in the
hydrothermal liquefaction (HTL) of water hyacinth at different reaction con-
ditions (temperature, reaction time, MNPs to biomass ratio and biomass to
water ratio). The best reaction conditions were as follows: temperature—
320˚C, reaction time—60 minutes, MNPs to biomass ratio – 0.2 g/g and bio-
mass to water ratio – 0.06 g/g. HTL in presence of MNPs gave higher biocrude
yields compared to HTL in absence of MNPs. The highest biocrude yield was
58.3 wt% compared to 52.3 wt% in absence of MNPs at similar reaction con-
ditions. The composition of biocrude oil was analysed using GC-MS and ele-
mental analysis. GC-MS results revealed that HTL in presence of MNPs led to
an increase in the percentage area corresponding to hydrocarbons and a re-
duction in the percentage area corresponding to oxygenated compounds, ni-
trogenated compounds and sulphur compounds. Elemental analysis revealed
an increase in the hydrogen and carbon content and a reduction in the nitro-
gen, oxygen and sulphur content of the biocrude when HTL was done in
presence of MNPs compared to HTL in absence of MNPs. The nanoparticles
were recovered from the biochar by sonication and magnetic separation and
recycled. The recycled MNPs were still efficient as HTL catalysts and were
recycled five times. The application of MNPs in the HTL of water hyacinth
increases the yield of biocrude oil, improves the quality of biocrude through
removal of hetero atoms, oxygen and sulphur compounds and is a potentially
economical alternative to the traditional petroleum catalysts since MNPs are cheaper, widely available and can be easily recovered magnetically and recy-
cled. This will potentially lead to an economical, environmentally friendly
and sustainable way of producing biofuels from biomass.
Description
Keywords
Hydrothermal Liquefaction, Water Hyacinth, Magnetite Nanoparticles, Biocrude Oil
Citation
Egesa, D., Mu- lindwa, P., Mubiru, E., Kyomuhimbo, H.D. and Aturagaba, G. (2021) Hydrothermal Liquefaction of Water Hyacinth: Effect of Process Conditions and Magnetite Nano- particles on Biocrude Yield and Composi- tion. Journal of Sustainable Bioenergy Sys- tems, 11, 157-186